Read e-book online Anionic polymerization: principles and practical PDF

By Henry L. Hsieh, Roderic P. Quirk

ISBN-10: 0824795237

ISBN-13: 9780824795238

This paintings introduces the elemental theories and experimental equipment of anionic polymerization in addition to the synthesis, research and features of anionic polymerized items. It information the production of linear and branched polymers, random and block copolymers, graft and macromonomers, and lots of different elements. The paintings emphasizes the connection among basic ideas and advertisement applications.;College or college bookstores may possibly buy 5 or extra copies at a different scholar cost, to be had on request from Marcel Dekker, Inc.

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T. L. Brown, Accounts Chem. , 1, 23 (1968). 10. H. , 16, 681 (1963). 11. H. Dietrich, J. Organomet. , 205, 291 (1981). 12. W. J. Hehre, L. Radom, P. v. R. Schleyer and J. A. Pople, Ab Initio Molecular Orbital Theory, Wiley, New York, 1986, p. 401. 13. G. B. Ellison, P. C. Engleking and W. C. Lineberger, J. Am. Chem. , 100, 2556 (1978). 14. G. W. Spitznagel, T. Clark, J. Chandrasekhar, and P. v. R. Schleyer, J. Comput. , 3, 363 (1982). 15. B. M. Smirnov, Negative Ions, McGraw-Hill, New York, 1982.

Without encumbering counterions) carbanions is quite limited. , organometallic compounds in which the organic groups are formally attached to metal atoms by metal-carbon bonds). The term carbanionoid has been suggested to describe polar organometallic compounds [4]. X-ray crystallographic studies have provided the most detailed structural information available for a variety of carbanionic (generally organo-metallic) species [58]. It is generally assumed that these structures can be used as models for the corresponding species in solution.

III. Bonding in Organoalkali Compounds The unique characteristics of alkyllithium compounds as initiators and lithium as a counterion in anionic polymerization relative to other organoalkali compounds [1719] dictate a detailed consideration of their structure and bonding. 1 Structure of methyl carbanion and the pyramidal inversion process. 1) [8]. Organo- lithium compounds are unique among the organic derivatives of the alkali metals since they generally exhibit properties characteristic of both covalent and ionic compounds [4,20].

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Anionic polymerization: principles and practical applications by Henry L. Hsieh, Roderic P. Quirk

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